SYNTHESIS OF ALLYLNORBORNYL CARBOXYLATE BASED ON DICYCLOPENTADIENE

ПОЛУЧЕНИЕ АЛЛИЛНОРБОРНИЛКАРБОКСИЛАТА НА ОСНОВЕ ДИЦИКЛОПЕНТАДИЕНА

Стр.16-22

DOI: 10.32758/2782-3040-2026-0-1-16-22

УДК 547.361.3+547.599

V. S. Kadyrly, R. A. Rasulova, E. G. Makhmudova, M. D. Ibragimova, J. G. Ismailova,

Kh. M. Mammadova

(Y. H. Mamedaliyev Institute of Petrochemical Processes, Ministry of Science and Education of the Republic of Azerbaijan)

Abstract. The reaction of obtaining allyl norbornyl carboxylate based on a by-product of the pyrolysis process – dicyclopentadiene – was studied. By means of the Diels-Alder reaction – [4+2]-cycloaddition of allyl acrylate to cyclopentadiene formed during the decomposition of dicyclopentadiene – the reactive monomer allyl bicyclo [2.2.1] hept-5-ene-2-carboxylat was synthesized. The influence of various factors on the yield of the target product was studied and optimal conditions for the synthesis of allylnorbornyl carboxylate were found, under which the yield was 80%. The physicochemical properties of allylnorbornylcarboxylate has been studied, the structure determined by IR, ¹H and ¹³C NMR methods of analysis.

Keywords: dicyclopentadiene, cycloaddition, allyl acrylate, allyl norbornyl carboxylate.